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Abstract
A bicyclic analogue of β- d-mannopyranose with nitrogen atoms replacing the ring and glycosidic oxygen atoms has been prepared in a single step from 5- O-mesyl- d-mannofuranose by a process that likely involves double displacement and an epoxide intermediate. A similar but protected bicyclic analogue of 6-deoxy-β- l-gulopyranose has been prepared by an electrophilic cyclization reaction.
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