Abstract

Newly prepared [RuX(p-cymene)(bichep)]X, (X = I, Cl) and Ru(OAc) 2(bichep) (bichep = 2,2′-bis(dicyclohexylphosphino)-6,6′-dimethyl-1,1′-biphenyl) proved to be highly efficient catalysts for asymmetric hydrogenation of carbonyl compounds bearing phenylglyoxyloyl group under mild conditions.

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