Abstract
This is a study on the magnetism of a Fe2O3@MCM-41 composite made up of iron(III) oxide nanocrystals of average length size of 4 nm embedded in the channels of a MCM-41 mesoporous matrix. Through Mossbauer spectroscopy, X-ray absorption experiments and static and dynamic magnetic measurements, we identify the guest iron oxide entities as composed by exchange-coupled hematite (weak ferromagnetic WF) and maghemite (ferrimagnetic FiM) arranged in a string of beads configuration. The WF/FiM nanocrystals behave as independent particle moments that block as a whole below TB = 17 K. The log-normal energy barrier distribution function determined from relaxation measurements shows a maximum at an energy E = 200 K. We explore to what extent the contact between domains of the two coexisting oxides controls the magnetism of this biphasic nanosystem.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.