Abstract
AbstractBorane dimethylsulfide (BMS) was found to be an efficient hydride source for nickel‐hydride catalyzed reductive migratory hydrofunctionalization reactions. Catalytic reductive migratory hydroarylation and migratory hydroalkenylation were achieved with BMS in high yields and with excellent regioselectivity. A large‐scale experiment employing as little as 0.5 equivalents of BH3 ⋅ Me2S as the hydride source delivered the desired migratory hydroarylation product in high yield and selectivity.
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