Abstract

An attempt is made to quantitatively determine acidic and basic surface oxides on carbon blacks and also to monitor their acid and base strength distribution by direct potentiometric titrations in non-aqueous media. In contrast to direct titration procedures proposed so far, our method allows to distinguish clearly between several types of acidic surface oxides of different acid strength. This is mainly achieved by improvements of the non-aqueous titration media. The total contents of weakly and strongly acidic and also of basic oxides determined by this very fast method is comparable to results obtained by slow and laborious indirect titrations.

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