Abstract
Transition Metal Silyl Complexes, 52[1]. - Formation of Copper Silyl and Stannyl Complexes by Reaction of [Ph3PCuH]6 with HER3 (E = Si, Sn) [Ph3PCuH]6 was used as a source for the Ph3PCu fragment to prepare copper stannyl and silyl complexes. Reaction of [Ph3PCuH]6 with HSnPh3, HSiPh3 or HSiClPh2, respectively, and two equivalents of PPh3 yielded the complexes (Ph3P)3CuER3 (ER3 = SnPh3, SiPh3, SiClPh2).
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