Abstract
By a photochemical reaction of MeCpMn(Co)3 with Ph2PCH2CH2SiHR2 (R Me, Ph), phosphine complexes MeCp(CO)2MnPPh2CH2CH2SiHR2 (1) formed initially, yield MeCp(CO)(Ph2P)Mn(H)SiR2CH2 (2) upon further irradiation. In 2 the cis-arrangement of the phosphine and the silyl ligand is enforced by linking the two moieties together. X-ray structure analysis of 2a (R Me) shows, that the Mn,H,Si three-center bond is not significantly influenced by this arrangement of ligands.
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