Abstract
In the reaction of Cp 2WGl 2 with Li[Si(SiMe 3) 3] the dihydrid tungstenocene derivative [(Me 3Si) 3SiC 5H 4]WH 2 (3) is formed with a 56% yield. 3 crystallizes in space group P 1 , with a 918.0(4), b 1580.9(4), c 1621.2(7) pm, α 117.63(2), β 89.95(3), γ 94.39(3)° at −40° C. The dihedral angle between the Cp planes is 140.9°.
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