Abstract
Abstract Sporophores of Hygrocybe species (Agaricales) contain muscaflavin, a pigment recently isolated from Amanita muscaria. Spectroscopic and chemical evidence for its dihydroazepine structure 5a is presented, indicating a close biogenetic relationship to betalamic acid 6a. The chemical nature of the water soluble pigments of Hygrocybe is dis cussed
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