Abstract
The title compound, C15H5N2S2, crystallizes as a trans–cis conformer. The thione sulfur is in a trans position with the methyl pyridyl fragment with respect to the C—N bond but adopts a cis position with the benzyl ring across the C—S bond. The dihedral angle between the planar quinoline ring and the dithiocarbazate unit is 103.70 (1)°. The inclination of the dithiocarbazate unit with the benzyl group is 17.20 (1)°. There are strong π–π stacking interactions between pairs of dithiocarbazate units and also pairs of pyridine rings [3.27 (5) and 3.28 (5) Å, respectively]. A long-distance intermolecular N—H⋯N hydrogen bond [3.171 (2) Å] also stabilizes the structure.
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