Abstract

The reaction of benzyl­ammonium tetra­fluoro­borate and 18-crown-6 in a methano­lic solution yields the title compound, C7H10N+·BF4 −·C12H24O6O6, which displays a supra­molecular structure. The –NH3 + substituent of the benzyl­ammonium cation forms a 1:1 supra­molecular rotator–stator structure by N—H⋯O hydrogen-bonding inter­actions.

Highlights

  • Min Min ZhaoKey indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.002 A; R factor = 0.045; wR factor = 0.103; data-to-parameter ratio = 18.1

  • The reaction of benzylammonium tetrafluoroborate and 18crown-6 in a methanolic solution yields the title compound, C7H10N+ÁBF4ÀÁC12H24O6O6, which displays a supramolecular structure

  • Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: IM2207)

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Summary

Min Min Zhao

Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.002 A; R factor = 0.045; wR factor = 0.103; data-to-parameter ratio = 18.1. The reaction of benzylammonium tetrafluoroborate and 18crown-6 in a methanolic solution yields the title compound, C7H10N+ÁBF4ÀÁC12H24O6O6, which displays a supramolecular structure. The –NH3+ substituent of the benzylammonium cation forms a 1:1 supramolecular rotator–stator structure by N—HÁ Á ÁO hydrogen-bonding interactions. Related literature For similar crown ether clathrates, see: Akutagawa et al (2002); Kryatova et al (2004). For their ferroelectric properties, see: Zhang et al (2009); Ye et al (2009)

Data collection
DÁ Á ÁA
Rigaku SCXmini diffractometer
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