Abstract
In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp 2 atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H⋯Cl hydrogen bond and a C—H⋯π interaction. In the crystal, molecules are linked via C—H⋯Cl hydrogen bonds, forming chains along the a-axis direction.
Highlights
In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp2 atom of the 2-chloro-3dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry
Molecules are linked via C— HÁ Á ÁCl hydrogen bonds, forming chains along the a-axis direction
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp atom of the 2-chloro-3dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. There is a short C—HÁ Á ÁCl hydrogen bond and a C— HÁ Á Á interaction. Molecules are linked via C— HÁ Á ÁCl hydrogen bonds, forming chains along the a-axis direction. Related literature For the crystal structures of similar compounds, see: Moro et al (2004); Caires et al (2006); Mafud et al (2013)
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