Abstract
The title compound, C17H16N2S2, a dithiocarbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenylidine group. The 3-phenylprop-2-enylidene and dithiocarbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenylprop-2-enylidene and the benzyl group is 77.78 (7)°. In the crystal structure, molecules are linked by an N—H⋯S hydrogen bond and a weak C—H⋯S interaction involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C—H⋯π interactions.
Highlights
The title compound, C17H16N2S2, a dithiocarbazate derivative, adopts an EE configuration with respect to the C C and
Molecules are linked by an N—H S
Hydrogen bond and a weak C—H S interaction involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane
Summary
Experimental a Department of Chemistry, Rajshahi University, Rajshahi 6205, Bangladesh, b
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