Abstract
The preparation and properties of mono- and di-nuclear rhodium(I) complexes of general formulae RhClL 2(btzH), [Rh(μ-btz)L 2] 2, Rh 2(μ-btz)(μ-N 3)(L 2) 2 and Rh 2(μ-btz)(μ-SCN)(COD) 2 [L 2 = diolefin, (CO) 2 or (CO)(PPh 3)], and of the related tetranuclear derivatives are reported. The latter compounds have benzotriazolate ligands simultaneously bonded to three rhodium atoms.
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