Abstract
Amines are extensively present in biological systems and are abundantly used in research, industries and agriculture. Systematic detection and quantification of certain amines can help us in food quality control and diagnosis of many diseases. A Schiff base probe HL was designed and successfully synthesized. It was proposed as a sensor for the exclusive detection of 1, 3- diaminopropane through turn-on fluorescence response in a variety of solvents including water. Micromolar limits of detection was achieved in all these solvents. Mechanism of detection was proposed by investigating mass spectrometric and NMR results. These were corroborated with DFT/TD-DFT calculations. Spiking experiments performed in various real water samples revealed the potential of the sensor to be used in day-to-day applications. Paper strip experiments demonstrated the suitability of the probe for real-life applications.
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