Abstract
Electronic, IR and UV spectroscopy has shown that 2-(N-isatinomethylene)-3(2H)-benzo[b]thiophenone in solution displays photo- and solvatochromism as a result of reversible E → Z isomerization, and it readily undergoes alcoholysis of the lactam bond. The resulting aminovinyl ketones exist as mixtures of the thermodynamically stable E- and Z-isomers.
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