Abstract
Benzocyclobutenylidene- h 5-cyclopentadienyldicarbonyliron(II) hexafluorophosphate converts h 5-CpFe(CO) 2R (R = cyclo-C 3H 5, CH 2-cyclo-C 3H 5) to the respective allene and butadiene complexes whereas Ph 3C + primarily yields addition products; both carbenium ions add to h 1- allyl- and substituted h 1 -allyl-iron complexes with the exception of the 3,3-dimethylpropenyl complex which is converted in both cases to h 5-CpFe(CO) 2(CH 2CHCMeCH 2) +.
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