Abstract
In the structure of the title compound, (2,3,5,6,8,9,11,12,14,15-decahydro-1,4,7,10,13,16-benzohexaoxacyclooctadecine)potassium chlorochromate(VI), [K(C16H24O6)][CrClO3], the K+ cation is located approximately in the center of the crown ether cavity and is coordinated by two anions, one on each side of the macrocylic ring, one anion being related to the other by the symmetry operator (x, y − 1, z). One anion is bonded through O and Cl atoms and the other only by an O atom. As a result, in the crystal structure, polymeric chains, consisting of alternating anions and cations, are formed along the [010] direction.
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