Abstract
The structures of the title compounds, [(Ph) 3 Sn(SPh)] (I) and [(Ph) 2 Sn(SPh) 2 ] (II), where Ph=C 6 H 5 , have been determined by single-crystal X-ray diffraction experiments. In both, the Sn atom has a coordination number of four. The first compound presents a quite regular tetrahedral geometry about the Sn atom, while in the second a greater distortion from the ideal angle of 109.5 o is observed. The atomic distances and angles in the phenyl rings are in good agreement with those of a regular hexagon, larger distortions being observed in the second compound
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