Abstract
Triarylmethyl cations eliminate substituted benzene in the gas phase, upon activation. The mechanism of this process has been studied using deuterium labeling, substituent effects, and density functional theory calculations. It is shown that this apparently simple dissociation is in fact a complicated stepwise process that involves several consecutive hydride shifts. The combination of experimental evidence and computational results leads to a clear description of transition states and reaction intermediates.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the American Society for Mass Spectrometry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
