Abstract
In the title compound, (C6H10N2)[Co(C7H3NO4)2]·5H2O, the CoII ion is six-coordinated in an N2O4 environment by two pyridine-2,6-dicarboxylate (pydc) ligands, having a distorted octahedral geometry. The crystal packing is stabilized by intermolecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π interactions between the pyridine rings of the pydc ligands and between the pydc ligands and the benzene-1,3-diammonium cations, with centroid–centroid distances of 3.4575 (15) and 3.7521 (15) Å.
Highlights
H atoms treated by a mixture of independent and constrained refinement max = 0.34 e Å3
CoII ion is six-coordinated in an N2O4 environment by two pyridine-2,6-dicarboxylate ligands, having a distorted octahedral geometry
The crystal packing is stabilized by intermolecular N—H O, O—H O and weak C—H O
Summary
Benzene-1,3-diammonium bis(pyridine2,6-dicarboxylato-j3O2,N,O6)cobaltate(II) pentahydrate Hossein Aghabozorga and Behrouz Notashc a Department of Chemistry, Islamic Azad University, North Tehran Branch, Tehran, Iran, bDepartment of Chemistry, Basic Science Faculty, East Tehran Branch, Islamic R factor = 0.055; wR factor = 0.113; data-to-parameter ratio = 16.5.
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