Abstract
In the title compound, C7H7NO·C6H3N3O7, one of the nitro groups of the picric acid molecule lies in the plane of the attached benzene ring [dihedral angle = 1.4 (1)°] while the other two are twisted away by 9.9 (1) and 30.3 (1)°. In the benzamide molecule, the amide group is almost coplanar with the benzene ring [dihedral angle = 4.4 (1)°]. An intramolecular O—H⋯O hydrogen bond generates an S6 ring motif. In the crystal, molecules are linked into a ribbon-like structure along the b axis by O—H⋯O and N—H⋯O intermolecular hydrogen bonds. In addition, C—H⋯O hydrogen bonds and short O⋯O contacts [2.828 (2) Å] are observed.
Highlights
C7H7NOC6H3N3O7, one of the nitro groups of the picric acid molecule lies in the plane of the attached benzene ring [dihedral angle = 1.4 (1) ] while the other two are twisted away by 9.9 (1) and 30.3 (1)
The amide group is almost coplanar with the benzene ring [dihedral angle = 4.4 (1) ]
Symmetry codes: (i) −x, y+1/2, −z+1/2; (ii) −x+1, −y+1, −z+1; (iii) −x+1, y−3/2, −z+1/2
Summary
C7H7NOC6H3N3O7, one of the nitro groups of the picric acid molecule lies in the plane of the attached benzene ring [dihedral angle = 1.4 (1) ] while the other two are twisted away by 9.9 (1) and 30.3 (1). The amide group is almost coplanar with the benzene ring [dihedral angle = 4.4 (1) ]. An intramolecular O—H O hydrogen bond generates an S6 ring motif. Molecules are linked into a ribbon-like structure along the b axis by O—H O and N—H O intermolecular hydrogen bonds. C—H O hydrogen bonds and short O O contacts [2.828 (2) Å] are observed
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta crystallographica. Section E, Structure reports online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
