Bentonite-Acrylamide Hydrogels Prepared by the Nonmixing Method: Characterization and Properties.

Abstract

A significant amount of research has been conducted on bentonite–acrylamide hydrogels. These gels are usually prepared by uniformly mixing bentonite with reactive monomers. Herein, a new preparation method of bentonite–acrylamide hydrogels has been proposed to cater to one novel application of bentonite–acrylamide hydrogels. In this method, bentonite–acrylamide hydrogel was obtained by pressing bentonite into a thin mud cake and extruding a mixed liquor of acrylamide, a cross-linking agent, an initiator, and water into the thin mud cake and then subjecting the system to water-bath curing. The effects of extrusion pressure, extrusion time, and acrylamide concentration on the tensile strength and elemental composition of bentonite–acrylamide hydrogel were investigated. The results show that the tensile strength of the bentonite–acrylamide hydrogel first increased and then tended to be stable with the further increase in extrusion pressure and extrusion time. As the concentration of acrylamide increased, the tensile strength of the bentonite–acrylamide hydrogel increased first and then decreased slightly. With the increase in extrusion pressure, extrusion time, and acrylamide concentration, the contents of C and N elements in the thin mud cake gradually increased and then tended to be stable, which reflects the state of the monomer entering the thin mud cake. In addition, the elemental composition of the bentonite–acrylamide hydrogel was analyzed via the scanning electron microscopy–energy dispersive X-ray spectrometry method, and it was found that the composition of the hydrogel was relatively uniform in the direction of mixed liquor extrusion.