Abstract
Bentonite beds are fairly common in both marine and terrestrial Upper Cretaceous (Campanian–Maastrichtian) deposits of the Western Interior Basin of western Canada and northwestern United States. A detailed stratigraphic, sedimentologic, geochemical (X-ray fluorescence), and mineralogical (X-ray diffraction) study of twenty-one bentonites from the Puskwaskau and Wapiti formations in the Grande Prairie area (west-central Alberta, Canada) is here presented. Major and trace-element concentrations from altered volcanic ashes document the presence in the study area of predominantly trachyandesitic and rhyolitic volcanogenic products, resulted from intense volcanic arc to within-plate pyroclastic activity. Concentration values of high field strength elements (HFSE) and selected large ion lithophile elements (LILE) (e.g. Nb, Zr, Th, and Y) obtained by X-ray fluorescence spectroscopy strongly support the presence of multiple volcanic sources. Integrated paleoenvironmental and geochemical criteria for provenance determination indicate a bimodal occurrence of basic and acid volcanic products interpreted as reflection of source areas characterized by different tectonic setting and magmatic composition. A comparative analysis of geochemical compositions between Grande Prairie bentonites and 30 known volcanic beds from central and southern Alberta, Manitoba and Montana 1. documents a trend toward more acidic and alkali-depleted volcanic products during the late Campanian–early Maastrichtian interval, and 2. suggests a well constrained stratigraphic and geographic subdivision of the non-marine successions of the foreland basin on the basis of geochemical characteristic of volcanic ash beds. Furthermore, geochemical “fingerprints” of several decimeter to meter thick bentonite beds have been coupled with volcanic ash subsurface signature in order to investigate their role as marker beds. This multiple-approach provides a reliable tool for basin-scale identification and correlation of non-marine sedimentary successions.
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