Abstract
AbstractWe analysed by raster electron microscopy Luttinger‐polyacetylene as a powder and as a film, both in pristine and (SbF6−‐electrochemically) doped form. The samples had been intensively washed with MeOH/HCl. One sample had, according to the results of transmission electron microscopy, fiber morphology. All samples show globules as primary structure arranged in clusters (in powder), mono‐layers, or chains (in film) (which previously led to “fibril theory”). The primary spherical particles have diameters from 0,02–0,05 μm. The “fibril” sample has very small spherical primary particles, which may develop using low catalyst amounts. Our results support that the conductivity characteristics is governed by phenomena antiparallel to the chain direction (change‐transfer‐complexes).
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