Behaviour and speciation of inorganic trace pollutants in a coal-fired power plant equipped with DENOX-SCR-ESP-NH3FGD controls

Abstract

The behaviour and speciation of inorganic trace pollutants were studied in a 270 MWh coal-fired power station equipped with denitrification (DeNOx)-based selective catalytic reduction (SCR), electrostatic precipitators (ESP) and ammonia flue gas desulphurisation (NH3-FGD) controls. The aqueous (NH4)2SO4 slurry (pH 3.2) showed remarkably high concentrations of SO42−, Cl−, Fe, NH4+, PO43−, and F− and was substantially enriched in multiple trace pollutants, e.g. Mn, Ni, Zn, and As, which can be ascribed to the diffusion of gaseous pollutants released during combustion and to the partial dissolution of fly ash (FA) particles entrained in the flue gas FGD. These processes were favoured by the iteration of the FGD water re-circulation cycles within the scrubber. Three major unresolved performance issues remain for the NH3-FGD with respect to the retention efficiency of major and trace pollutants: (i) the high concentration of soluble salts and major and minor trace elements in the aqueous (NH4)2SO4 slurry could lead to entrainment of droplets and particles with the outgoing (OUT)-FGD gas; (ii) the ionic strength, as a result of the high concentration of the elements associated with soluble salts and major and minor elements, could lead to diminishing diffusivity of gaseous pollutants into the aqueous phase, where these are supposed to dissolve; and (iii) the acidic conditions of the aqueous (NH4)2SO4 slurry, caused by Fe-hydrolysis, could lead to low FGD efficiencies. Operating conditions at this power station affect Hg partitioning and fate across the PCC-SCR-ESP-NH3-FGD.