Abstract

The extraction behavior of several lanthanide and actinide elements in the reductive-oxidative extraction process in a molten salt/liquid metal system is described. The equilibrium distributions of the elements are affected by metal composition as well as by salt composition. The effect of salt composition is due to the formation of complex compounds in the salt phase. The influence of metal composition is the result of intermetallic compounds in the metal phase. The extraction rates of the elements from the salt phase to the metal phase were also studied from the standpoint of mass transfer and chemical reaction at the interface between the two phases.

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