Abstract
The experimental rate laws for the oxidation of N-acetylglucosamine with bromamine- B are: − d[BAB]/dt = k/ [BAB]1 [GlcNAc]0.69 [HClO4]−0.76 [IrCl3]0.48 [BSA]−0.33 in acid medium and –d[BAB]/dt = k/ [BAB]1 [GlcNAc]1 [NaOH]0.79 in alkaline medium. The IrCl3 catalyzed reaction is thirteen fold faster than uncatalyzed reaction. Appropriate mechanisms and rate laws were deduced. The reaction of N-acetylglucosamine with Bromamine-B in acid and alkaline medium is
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