Abstract

A sodium-sulfur cell was constructed with sodium polysulfide circulating in a narrow annulus around a β-alumina tube. The absence of carbon mat in the electrode reduced the current collector surface area appreciably, localized the electrochemical reactions, and ultimately led to film formation on the electrode. The results are consistent with existing models and interpretations of sulfur electrode behavior. Film formation on the electrode is responsible for the rather poor electrical characteristics of the cell.

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