Bead-like cobalt nanoparticles coated with dielectric SiO2 and carbon shells for high-performance microwave absorber

Abstract

The development of high-efficiency microwave absorption materials with both strong absorption intensity and wide absorption bandwidth is still a significant challenge. In this work, the bead-like cobalt nanoparticles of 50 nm with strong magnetic loss capability are prepared by hydrogen plasma-metal reaction. To further regulate the dielectric parameters, the carbon, SiO2, and SiO2/carbon shells are coated on the bead-like cobalt cores by in-situ polymerization of silica and phenolic resin to obtain the Co@C, Co@SiO2, and Co@SiO2@C nanocomposites, respectively. The Co@SiO2@C nanocomposite possesses the best electromagnetic wave (EMW) absorption performances among the samples. At the thickness of only 1.7 mm, the minimum reflection loss (RL) value of −39.6 dB at 13.5 GHz and the effective absorption bandwidth (EAB) of 7.6 GHz for RL < −10 dB are simultaneously obtained. Surprisingly, the absorption bandwidth (RL < −20 dB) is as wide as 14.2 GHz (3.8–18 GHz) with the thickness of 1.3–5.0 mm. The excellent microwave absorption performances are ascribed to the strong magnetic loss of the bead-like Co, the synergistic effect between multiple components, as well as the multiple polarization and multiple scattering induced by core–shell structure. As a consequence, the Co@SiO2@C nanocomposite can serve as an ideal candidate for high-performance microwave absorption.