BCP의 증착 조건에 따른 광학적 특성 및 전도 기구에 미치는 영향

Abstract

In a triple-layered structure of ITO/N,N'-diph enyl-N,N'bis(3-methylphenyl)-1,1' - biphenyl-4,4'-diamine(TPD)/tris(8-hydroxyquinoline)aluminum(<TEX>$Alq_3$</TEX>)/(2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline(BCP)/Al device, we have studied the electrical and optical characteristics of organic light-emitting diodes(OLEDs) depending on the deposition condition of BCP layer. Several different sizes of holes on boat and several different deposition rates were employed in evaporating the organic materials. And then, electrical properties of the organic light-emitting diodes were measured and the performance of the devices was analyzed. It was found that the hole-size of crucible boat and the evaporation rate affect on the surface roughness of BCP layer as well as the performance of the device. When the hole-size of crucible boat and the deposition rate of BCP are 1.2 mm and <TEX>$1.0\;{\AA}/s$</TEX>, respectively, average surface roughness of BCP layer is lower and the efficiency of the device is higher than the ones made with other conditions. From the analysis of current density-luminance-voltage characteristics of a triple layered device, we divided the conductive mechanism by four region according to applied voltage. So we have obtained a coefficient of <TEX>${\beta}_{ST}$</TEX> in schottky region is <TEX>$3.85{\times}10^{-24}$</TEX>, a coefficient of <TEX>${\beta}_{PF}$</TEX> in Poole-Frenkel region is <TEX>$7.35{\times}10^{-24}$</TEX>, and a potential barrier of <TEX>${\phi}_{FN}$</TEX> in Fower-Nordheim region is 0.39 eV.