Batteries or silos: Optimizing storage capacity in direct air capture plants to maximize renewable energy use

Abstract

Direct air capture (DAC) of carbon dioxide is among the technologies that is forecast to play a major role in achieving the global ambition to constrain atmospheric temperature rise to below two degrees Celsius by 2100. However, DAC is an energy intensive chemical process, whose designs are currently incompatible with intermittent renewable energy (RE) sources. This research develops a model to enable the flexible operation of DAC, to maximize RE usage. A new model of the chemical process flow of a liquid solvent DAC that includes silos to store CaCO3 and CaO is developed. A linear programming optimization model that minimizes energy costs while achieving the CO2 capture targets of the DAC plant is developed. Scenario analysis establishes the storage silo size and battery storage size needed to reduce renewable energy curtailment to zero for a given RE profile. Simulations with a representative 336-hour RE profile reveal that two silos of sizes 660 tons and 370 tons would be needed to support flexible DAC plant operations and reduce RE curtailment to zero. For the same profile, a 355 MWh/65 MW battery would be required to achieve zero renewable curtailment. The results demonstrate that flexible operation of DAC is achievable, and DAC plants can adapt to variable RE without the need for battery energy storage. Furthermore, considering the scale of storage needed to minimize RE curtailment in a commercial-scale DAC plant, the results suggest that using physical storage silos could be more cost-effective than using battery energy storage.