Batch Preparation of CuO/ZnO-Loaded Nanofiber Membranes for Photocatalytic Degradation of Organic Dyes.

Abstract

Composite nanofiber membranes (CNFMs) loaded with CuO/ZnO (CZCNFMs) have important applications in a series of organic and industrial catalytic reactions because of nanoeffects of the nanofibers and the peculiar performances of semiconductor oxides. In this work, CZCNFMs with different mass ratios of Cu to Zn were successfully fabricated in batches using modified bubble electrospinning (MBE), a heat treatment method, and a hydrothermal method. The influences of the mass ratio of Cu to Zn on the morphologies, structures, and properties of the CNFMs were studied, and the obtained CNFMs with different mass ratios of Cu to Zn were applied to the photodegradation of methyl orange (MO) and methylene blue (MB). The results showed that when the mass ratio of Cu to Zn was 5:5, the fabricated CNFM had better morphology, structure, and mechanical properties and had the best degradation effects on MO and MB. In addition, the principal active substances produced during the photodegradation of MO were defined by free radical capture experiments, and the influences of the pH value of the MO solution on the photocatalytic activity of the CNFMs with the optimal mass ratio of 5:5 were discussed.