Abstract
MSWI fly ash and municipal sludge are solid wastes. Melting vitrification treatment was a resource utilization method. However, the flow temperature of grate furnace MSWI fly ash and municipal sludge was high (>1325 °C), which increased the energy consumption in the melting process. MSWI fly ash contained a large amount of CaO, and municipal sludge contained a large amount of SiO2, Al2O3, and Fe2O3. The temperature of melting vitrification can be reduced using these two kinds of CITY garbage as raw materials to change the proportion of ingredients. The eutectic characteristics of MSWI fly ash and municipal sludge and the phase diagrams of CaO-SiO2-Al2O3 (C-S-A) and CaO-SiO2-Al2O3-Fe2O3 (C-S-A-F) were analyzed in this paper. It established a low melting point mixing system. The results showed that when the amount of municipal sludge was 50-70%, the flow temperature of the mixtures was <1215 °C, which was significantly lower than that of MSWI fly ash (1490 °C) and municipal sludge (1325 °C). The optimal range of low melting point components was 14.1-36.3% CaO, 21.6-40.4% SiO2, 6.7-12.6% Al2O3, and 6.3-11.4% Fe2O3. At 400-1400 °C, the minerals in the mixtures mainly changed as follows: CaCO3 + SiO2 + Al2O3 → Ca2SiO4 + Ca3SiO5 + Ca2Al2SiO7 + Ca3Al2O6 + Ca12Al14O33 → CaAl2Si2O8. In the melting experiment, with the increase in temperature, most of the phases in the mixtures might become amorphous. Therefore, the low melting point phase anorthite (CaAl2Si2O8) only accounted for a small part of the final molten product.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.