Abstract
The presence of natural organic matters (NOMs) will have a negative effect on the removal of small molecule organic contaminants in complex water quality, therefore, it’s very important to design a catalyst with size-exclusion function to achieve the selective removal of targeted pollutant. Herein, a novel ZIF-L catalyst precursor with lamellar stack structure is designed, and iron as heteroatom is doped in ZIF-L gaps named ZIF-L@Fe. After pyrolysis, Fe ions are transformed into Fe nanoparticles, and act as the active sites of catalyst. In order to verify the selective removal ability of resulted NSC@Fe in dielectric barrier discharge (DBD), tetracycline hydrochloride (TTCH) and humic acid (HA) is selected as the target pollutant and coexistence macromolecular interferent, respectively. In the presence of HA (50 mg/L), the degradation rate of TTCH in the system is not significantly affected (with HA, k = 0.037 min−1; without HA, k 0.036 min−1), which is mainly due to the layered material stacking characteristics (size-exclusion). The degradation mechanism and pathway are further confirmed by radical quenching experiments and liquid chromatography−mass spectrograph (LC−MS), respectively. This study is believed to shed new light on how to rationally design catalyst with selective removal of organic pollutants in complex water quality for water remediation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.