Base-Directed Formation of Isostructural Lanthanide-Sulfate-Glutarate Coordination Polymers with Photoluminescence.

Abstract

A series of five isostructural 3D lanthanide-based coordination polymers [LnIII2(H2O)6(glu)(SO4)2]n [Ln = Pr(1), Nd(2), Sm(3), Eu(4), and Gd(5)] was effortlessly obtained within a few minutes via the microwave-heating method. The employment of auxiliary bases, that is, sodium hydroxide, 4,4'-bipyridine, and 1,4-diazabicyclo[2.2.2]octane, led to the formation of the title complex, whereas base-free synthesis yielded a three-dimensional inorganic coordination polymer, [Ln2(H2O)4(SO4)3]n·nH2O, Ln = Nd (2a). The robustness of the synthetic method was illustrated as both microwave-heating and conventional hydrothermal techniques also enabled the formation of a high-crystalline phase-pure complex 1-5. In the structure of 1-5, glutarato (glu2-) and sulfato ligands link dinuclear Ln(III) building units into three-dimensional frames. The glu2- ligands act as tethering linkers, expanding the structure into a neutral 3D coordination network. Hydrogen bonds were found to be the predominant intermolecular interactions in the crystal structures. Photoluminescence of the complex 1-5 was studied.