Abstract
An interesting base-controlled protocol for the divergent and atom-economic synthesis of benzo[b]fluorenones and benzo[b]fluorenols with the great diversity in substitution patterns has been developed. Started from readily available 1,6-enynes, good to excellent yields of the corresponding tetracyclic benzo[b]fluorenones and benzo[b]fluorenols can be chemoselectively achieved under metal-free conditions. Notably, only K2CO3 or Et3N was required as the promoter here and the reaction can work well in a high-selective manner.
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