BaRuO3 coated Ti plate as an efficient and stable electro-catalyst for water splitting reaction in alkaline medium

Abstract

Water splitting using an electrochemical device to produce hydrogen fuel is a green and economic approach to solve the energy and environmental crisis. The realistic design of durable electro-catalysts and their synthesis using a simplistic technique is a great challenge to produce hydrogen by water electrolysis. Herein, we report a stable highly active barium ruthenium oxide (BRO) electro-catalysts over Ti plate using a soft chemical method at low temperature. The synthesized material shows facile hydrogen evolution reaction (HER) as well as oxygen evolution reaction (OER) in alkaline medium with over-potentials of 195 mV and 300 mV, respectively at a current density of 10 mA cm−2. The excellent stability lasts for at least 24 h without any degradation for both the HER and OER at the current density of 10 mA cm−2, inferring the practical applications of the material toward production of green hydrogen energy. Certainly, the synthesized catalyst is capable adequately for the overall water splitting at a cell voltage of 1.60 V at a current density of 10 mA cm−2 with an impressive stability for at least 24 h, showing a minimum loss of potential. Thus the present work contributes to the rational design of stable and efficient electro-catalysts for overall water splitting reaction in alkaline media.