Abstract

The band structures of GeSe, GeS, SnSe and SnS layered semiconductor compounds have been calculated by the EO LCAO method in a single-layer approximation. The Madelung energy of electron in the field of all lattice ions was taken into account. The results of band-structure and density-of-states calculations are in good agreement with earlier calculations carried out by the pseudopotential method. It is shown that, unlike Ge chalcogenides, the minimal energy gap for Sn chalcogenides is situated on the symmetry line Lambda (k, 0, 0) and not on V(0, 0, k). The effective masses of electrons and holes near band extrema have been calculated.

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