Banded texture in sheared a semiflexible thermotropic liquid-crystalline polyester and its graft copolymers with polyolefins

Abstract

The formation of banded texture both in a semiflexible thermotropic liquid-crystalline polyester (SBH 112, synthesized from sebacic acid, 4,4′-dihydroxybiphenyl and 4-hydroxybenzoic acid, from Eniricerche, Milan) and in a blend of SBH with graft copolymers, consisting of a polyolefin (polyethylene or polypropylene) backbone and SBH grafts (COPPE, COPPP) has been studied by polarization microscopy and by scanning electron microscopy. The influence of the preparation conditions upon the perfection, characteristics and thermal stability of the banded texture has been investigated. The results show that the banded texture formed in SBH sheared films possesses greater perfection, smaller band width and larger angle of deviation, and higher thermal stability than the banded texture formed in COPPE and COPPP prepared under similar conditions. It has been assumed that the chain rigidity of the macromolecules of the system is mainly responsible for the formation and perfection of the banded texture.