Abstract
AbstractThe band structure of an infinite linear polyaniline is investigated by using the HCO approximation. The degree of modelling of the limiting structure for the series by the linear oligomers so far synthesized is investigated. The upper bound of the wave‐length of the long‐wave ultraviolet absorption band for the limit is found, and the possibility of estimation of the conduction properties of its complex with iodine is indicated. The problem of replacement of the NH group in the chains by a more general group X is dealt with, and the dependence of the energy gap between the highest occupied and the lowest unoccupied band on the parameters of this group is determined.
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