Abstract
The shape of the ν 1 and ν 3 Raman bands of N 2O has been studied in the presence of argon at various pressures and also when N 2O was dissolved in several inert liquids. We show that there is evidence for motional narrowing of the Q branch of the isotropic part of the ν 1 and ν 3 Raman bands due to collisions with the perturbing gas and to interactions with the solvent. The anisotropic part of the Raman scattering is also analysed and explained by the transition from the almost free rotation in the gas systems to diffusional rotation in the most strongly perturbing solvent system.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
