Band intensities in the circular dichroism and absorption spectra and the states of d ions in absorbing media: I. Octahedrally coordinated positions of d ions

Abstract

The factors affecting the band intensity in circular dichroism (CD) and absorption spectra (selection rules, point group of structural position, and the electron density of the ground state of octahedrally coordinated d ion in absorbing medium) are considered. The intensities of CD and absorption bands are calculated and compared with the experimental data. It is shown that the differences in the spatial inversion of the electric- and magnetic-dipole moment transformations lead to a more rigorous validity of the symmetry selection rules and increase the resolution of peaks and transparency window of medium absorption in CD spectra (in contrast to absorption ones). Some criteria for estimating the valence and structural states of d ions are formulated.