Bamboo cellulose-derived activated carbon aerogel with controllable mesoporous structure as an effective adsorbent for tetracycline hydrochloride.

Abstract

Activated carbon has been widespread applied in the removal of pollutants in wastewater. However, many biomass-derived activated carbon suffer from the challenge of controllable pore size regulation, hindering their efficient adsorption of pollutants. Herein, bamboo-derived activated carbon aerogel (BACA) has been successfully prepared through KOH high-temperature activation of cellulose aerogel which was prepared using cellulose extracted from bamboo. Bamboo cellulose aerogel provides sufficient reaction sites for KOH, which is conducive to the formation of a mass of mesoporous structures on the pore walls of the activated carbon aerogel. The optimal BACA adsorbent shows high specific surface area (2503.80 m2/g), and maximum adsorption capability for tetracycline hydrochloride (TCH) reaches 863.8mg/g at 30 ℃. The removal efficiencies of TCH are 100% and 98.4% at 40 ℃ when the initial concentrations are 500 and 700mg/L, respectively. Adsorption kinetics and isotherm indicate that the adsorption of BACA for TCH is monolayer adsorption based on chemical adsorption. Spontaneous and endothermic adsorption processes are proved by adsorption thermodynamic studies. Additionally, coexisting ions have insignificant effect on TCH adsorption, and the BACA sample displays excellent adsorption property for five reuse cycles with a removal efficiency of 80.95%, indicating the outstanding adsorption capacity of BACA in practical application. The excellent adsorption performance provides BACA with a promising perspective to remove TCH from wastewater, and the prepared method of BACA can be widely extended to other biomass materials.