Abstract

Replacing platinum for catalyzing hydrogen evolution reaction (HER) in acidic medium remains great challenges. Herein, we prepared few-layered MoS2 by ball milling as an efficient catalyst for HER in acidic medium. The activity of as-prepared MoS2 had a strong dependence on the ball milling time. Furthermore, Ketjen Black EC 300J was added into the ball-milled MoS2 followed by a second ball milling, and the resultant MoS2/carbon black hybrid material showed a much higher HER activity than MoS2 and carbon black alone. The enhanced activity of the MoS2/carbon black hybrid material was attributed to the increased abundance of catalytic edge sites of MoS2 and excellent electrical coupling to the underlying carbon network.

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