Abstract
Just as the far side of the moon remains mysterious, the mechanism of Kahne glycosylation is still not fully understood and remains a 30‐year puzzle, especially when it comes to the ultimate fate of the leaving group. This work disclosed the unknown transformations of glycosyl sulfoxide activation process in Kahne glycosylation and related reactions. It supplied a new insight into sulfoxide chemistry. More details are discussed in the article by Wan et al. on page 383—391.image
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