Abstract
Herein, we present our work on the synthesis and characterization of novel vanadium complexes supported by a trisamidophosphine ligand, with a focus on their ability to activate dinitrogen. The tetra‐dentate sites and wiggled arylamine substituents in the [PN3] ligand guarantee to support the vanadium center with different oxidation states and bind several small molecules in the apical pocket. More details are discussed in the report by Shi et al. on pages 39—45. image
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