Abstract
Advanced Synthesis & CatalysisVolume 355, Issue 7 p. 1436-1436 Cover PictureFree Access Back Cover: (Adv. Synth. Catal. 7/2013) First published: 10 May 2013 https://doi.org/10.1002/adsc.201390013AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract The cover picture, provided by Huang and co-workers, depicts a cooperative catalysis with aldehyde and copper for the aerobic oxidative CH amination of azoles. The aldehyde acts as a catalyst to activate the amine to form aminal A, which then reacts with CuBr2 to generate the copper-amide B and regenerate the aldehyde to complete the aldehyde catalysis. Copper-amide B reacts with benzoxazole to generate organocopper B via CH activation. Subsequent reductive elimination provides the desired product and releases Cu(I), which is oxidized by O2 to afford Cu(II) and complete the catalysis. This cooperative catalysis is illustrated in the full paper by Huang and co-workers on pages 1315--1322. Volume355, Issue7May 3, 2013Pages 1436-1436 RelatedInformation
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