Abstract
Late Paleozoic blueschists present good exposures in the Pateyar metamorphic complex (south of Chupanan, Isfahan Province). They are formed by metamorphism of primitive basaltic lavas. Petrography and microprobe analyses show that the studied rocks consist of glaucophane, actinolite, actinolitic hornblende, plagioclase (albite), sphene, magnetite, quartz and apatite. Secondary minerals are epidote, chlorite, pyrite, hematite and calcite. Mineralogical assemblages are consistent with blueschist facies metamorphism, which is followed by a retrograde metamorphism in greenschist facies. Estimation of the metamorphic conditions suggests 300–400°C and 7–11 kbar. Chemical signatures of the studied metamorphic rocks conclude that they retain main geochemical characteristics of the protoliths, which allow the petrochemical interpretations. Geochemical analyses of these blueschists show that they were originally tholeiitic basalts. Evident negative anomalies of Nb, Ta and Ti relative to Th, La and Ce, in the primitive mantle normalized spider-gram, reveal subduction role in their petrogenesis. The studied metavolcanics exhibit an intermediate chemistry between the N-MORB (normal mid-ocean ridge basalt) and IATB (island arc tholeitic basalt). Enrichment in LREE (light rare earth elements) and LILE (large ion lithophile elements) and relative depletion in HFSE (high field strength elements) suggest a back-arc basin paleotectonic setting for the Chupanan samples. The primitive magma of the analyzed samples possibly have been produced by 8–13% melting of a spinel lherzolite. The field and petrological data propose that the studied Paleozoic metavolcanics were formed in a back-arc basin above the northward subduction of Paleo-Tethys oceanic lithosphere in Central Iran. The chemical criteria of the LILE/HFSE ratio suggests that the subduction zone was young and immature during the volcanism.
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