Abstract
Red transparant platelet-shaped single crystals of tetrabarium gallium trinitride oxide, Ba4GaN3O, were synthesized by the Na flux method. The crystal structure is isotypic with Sr4GaN3O, containing isolated triangular [GaN3]6− anionic groups. O2− atoms are inserted between the slabs of [Ba4GaN3]2+, in which the [GaN3]6− groups are surrounded by Ba2+ atoms.
Highlights
Sr4GaN3O, containing isolated triangular [GaN3]6 anionic groups
O2 atoms are inserted between the slabs of
[Ba4GaN3]2+, in which the [GaN3]6 groups are surrounded by Ba2+ atoms
Summary
R factor = 0.043; wR factor = 0.099; data-to-parameter ratio = 22.2. Red transparant platelet-shaped single crystals of tetrabarium gallium trinitride oxide, Ba4GaN3O, were synthesized by the. Sr4GaN3O, containing isolated triangular [GaN3]6 anionic groups. O2 atoms are inserted between the slabs of [Ba4GaN3]2+, in which the [GaN3]6 groups are surrounded by Ba2+ atoms
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